Measurement of Depression of Freezing Point

Measurement of Depression of Freezing Point

Measurement of Depression of Freezing Point

The arrangement for cryoscopic determination of molar mass of a solute is shown in Figure.

The apparatus essentially consists of a freezing tube F fitted with a stirrer S and side tube A. The freezing tube is surrounded by an air jacket J to reduce the rate of cooling. The Beckmann thermometer is introduced into the freezing tube through an opening at the rubber or velvet cork fitted at the open end of the freezing tube. The entire assembly is then placed in an ice bath, B, kept at a temperature of 3 – 50 C below the freezing point at the solvent.

Figure: Apparatus for cryoscopic measurements

The depression of freezing point is determined first by recording the Beckmann reading corresponding to the freezing point of the pure solvent, and then that of the solution. The molar mass of the solute is determined by using the equation since all the quantities are now known.

In cryoscopic method uniform stirring of the solvent (or solution) is an important step. The solvent is stirred uniformly and slowly by the stirrer S, otherwise incorrect result may be obtained due to supercooling. The temperature gradually falls as the solvent cools down. At one point the thermometer will show a rapid rise of about 0.2 – 0.3°C, after which the mercury meniscus will remain steady for a considerable time. The sudden rise is due to initial supercooling, but as soon as a small amount of solid phase is formed the system quickly goes back to the true fleecing point indicated by the constant reading of the thermometer. This is the true freezing point of the solvent shown as cd in Figure.

Figure: Time vs temperature during cooling

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