Stoichiometry of Electrolysis

Stoichiometry of Electrolysis

Michael Faraday found that the mass of substances released at the electrodes is directly related to the total charge that has passed through the electrical…
Electrolysis of Molten Salts

Electrolysis of Molten Salts

A Downs cell is a commercial electro- chemical cell used to obtain sodium metal by electrolysis of molten NaCI. A number of other reactive metals…
What is Electrolytic Cell?

What is Electrolytic Cell?

An electrolytic cell is an electro-chemical cell in which an electric current drives an otherwise non-spontaneous reaction. Note that the electrolytic cell requires an external…
What is Fuel Cell?

What is Fuel Cell?

A fuel cell is a device that generates electricity by a chemical reaction. A proton-conducting polymer membrane (the electrolyte) separates both the anode and cathode…
Storage Cell

Storage Cell

The lead storage cell (a rechargeable cell) consists of electrodes of lead alloy grids; one electrode is packed with a spongy lead to form the…
Leclanche Dry Cell

Leclanche Dry Cell

The Leclanche dry cell, or zinc-carbon dry cell, is a voltaic cell with a zinc can as the anode and a graphite rod in the…
Rusting in Electro-Chemistry

Rusting in Electro-Chemistry

Rusting of iron consists of the formation of hydrated oxide. Look at the following two half equations: Fe2+ (aq) + 2e– → Fe(s)                       E° = -0.44…
Strengths of Oxidising and Reducing Agents

Strengths of Oxidising and Reducing Agents

Standard electrode potentials are useful in determining the strengths of any oxidising and reducing agents under standard-state conditions. – A reduction half-reaction has the general…
Predicting Reactions in Electro-Chemistry

Predicting Reactions in Electro-Chemistry

Standard reduction potential E° values can be used to predict whether a redox reaction will happen spontaneously or not. Find the standard reduction potential of…
How to Calculate Ecell or Electro Motive Force Cell

How to Calculate Ecell or Electro Motive Force Cell

Consider the zinc-copper cell, how can the emf of such a cell be calculated from the standard potentials, rather than by experiment? The two half-reactions…
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