Explain the causes of deviation of real gases from ideal behavior Causes of Deviations of Real gas from ideal Behavior From, the Amagat’s curve we know that real gases deviate from ideal behavior. This deviation can…
What is gas? Gas is a physical state of matter at normal temperature and pressure. In this state the translational motion of molecules is greater than their intermolecular…
Explain 1 s Electron of the Hydrogen Atom with Integration The probability P that an electron is a distance r from the nucleus is called the radial distribution function. The hydrogen atom’s is electron radial…
Integration Quantum Mechanics of Conjugated Polyene Molecule A polyene molecule is a linear hydrocarbon chain of alternating single and double bonded C-atoms. Polyene molecules are important in biological processes and below Figure…
Enthalpy of Molecule and Temperature Changes with Integration The enthalpy of a molecule, H, changes by dH when the temperature, T, changes by dT and the change is commonly given as a polynomial…
Ideal Gas Expansion with Integration We have one mole of ideal gas at an initial volume of 4.90×103 cm3 which expands to a final volume of 2.45×104 cm3 at a…
Describe Expanding Gas and Thermodynamic Work In Chemistry it is very common to have gases being formed, reacting, compressed or expanding. A simple way of understanding such processes is to begin…
Explain Second-Order Chemical Reactions with Intregration If the overall (or stoichiometric) reaction is two molecules of A reacting to give products 2A → P with rate constant k then for some…
Explain Radioactive Decay with Integration The decay of a radioactive element A → P has a rate constant k. Radioactive decay is a first-order chemical reaction with [A] and t…
Explain Consecutive Chemical Reactions with a Rate Determining Step [B] = [A]0 [k1 /(k2 – k1) (e-k1t – e-k2t) By consideration of each of the terms of the equation find approximate expressions for [B]…